Synthesis and Crystal Structure of Copper(I) Nitrate π-complex with 1-allylbenzotriazole of Equimolar Composition.

The CuNO3 • C6H4N3(C3H5) compound (I) was obtained by alternating current electrochemical synthesis, starting from an ethanol solution containing Cu(NO3)2 • 3H2O and a mixture of 1- and 2-allylbenzotriazole titrated by HNO3 to pH = 4. The C=C bond of one 1-allylbenzotriazole molecule, the nitrogen atom from another ligand moiety, and two oxygen atoms from two nitrate-anions form a trigonal-pyramidal environment of the metal atom. The bridging function of the ligand moiety results in infinite metal-organic chains, interconnected by weak CH…O hydrogen bonds, π-π and π-σ stacking and van der Waals interactions.